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CORE SATURATION - OIL AND WATER

CORE Fluid saturations
Saturation of a particular fluid is the proportion of that fluid compared to the porosity:
       1: Swtr  = Vwtr / PHI
       2: Soil   = Voil / PHI
       3: Sgas = Vgas / PHI
       4: Swtr + Soil + Sgas = 1.00

In the laboratory, it is easier to measure weight (mass) than volume, although both are often recorded.
       5: Fluid weight = Weight water + Weight oil + Weight gas
 OR 6: Fluid weight = DENSwtr * Vwtr + DENSoil * Voil + DENSgas * Vgas
 OR 7: Fluid weight = PHI * (DENSwtr * Swtr + DENSoil * Soil + DENSgas * Sgas) 

Saturations determined from core analysis are full of problems, but the measurements can be useful for certain situations. The problems are related to the fact that usually cores are flushed, at least to some degree,  by mud filtrate during the coring process. This means that much of the hydrocarbon is removed and replaced by mud filtrate. Formation water in the core is also altered by invasion. In water based muds, a tritium tracer can be used while coring. This allows the lab to select samples with the least invasion, based on the tritium remaining in the core.

Plastic sleeve coring or wrapping of the core upon retrieval reduces gas loss and water evaporation. Properly handled and measured in the lab, both residual oil and water saturations can be useful qualitatively, and often even quantitatively. In an oil zone, the residual water saturation from core may reflect the irreducible water saturation in the zone, or at least the actual saturation in a transition or depleted zone. The residual oil represents the saturation to expect after an efficient water flood or aquifer drive.

Cores taken in oil based mud give a better view of irreducible water, as these muds do not displace the water. However, gas expansion still distorts the oil volume.ines are log analysis.


Bakken “Tight Oil” example showing core porosity (black dots), core oil saturation (red dots). core water saruration (blue dots), and permeability (red dots). Note excellent agreement between log analysis and core data. Separation between red dots and blue water saturation curve indicates significant moveable oil, even though water saturation is relatively high. Log analysis porosity is from the complex lithology model and lithology is from a 3-mineral PE-D-N model using quartz, dolomite and pyrite.

The main use for core analysis oil saturation is to estimate minimum possible residual oil saturation, and to assist in locating gas-oil and oil-water contacts. Gas and water zones have low residual oil, unless they were once oil zones (recently or in earlier geologic time). Oil saturation from core analysis is quite useful in tar sand and sometimes in heavy oil evaluations, where flushing is minimal.

Cores are stored in boxes on shelves in warehouses. In hot climates, I have seen oil leaking from core to core, making the presence of oil in a core somewhat equivocal.


CORE saturation measurements
A common method for direct measurement of saturation in a core sample is the distillation retort method. Core samples are heated, fluids are vaporized and condensed into a graduated glass receptacle. This is a rapid method to determine oil and water volumes. Unfortunately, high temperature (1100 F) may destroy the sample and drives off clay bound water (CBW). Clay bound water may be estimated by observation of water volume versus time - pore water is recovered first and clay bound water later, as the temperature increases..


 

In a core drilled with water base mud, the oil volume is divided by the porosity to obtain a residual oil saturation. Similarly, a water saturation is determined but the sum of Soil + Swtr will not equal 1.00 due to evaporation of water prior to the measurement. In an oil based core, the sum of fluid volumes gives total porosity (PHIt).

In both cases, coking and cracking of the oil reduces oil volume, resulting in low estimated oil saturation. Core lab companies scale the recovered oil by a factor to account for this. The scale factor (KSF) varies from about 1.08 for light oil to 1.28 for heavy oil. Final results are calculated from:
       8: Swtr = (Vwtr - CBW) / PHIe
       9: Soil = (Voil * KSF) / PHIe

PHIe is usually determined by an independent lab method from a very nearby core sample.

The solvent extraction method is somewhat similar. The core sample is held in a thimble above a source of solvent, which is heated. The solvent vapour mobilizes the water, dissolves the oil, and all are condensed, recovered, and measured.

The method gives an accurate water saturation, can be done as part of the core cleaning process, and is non-destructive. The method is slow and can take several days. Oil saturation is determined by an indirect method, as follows:
       10: Swtr = Vwtr / PHIe
       11: Voil = ((WTinit - WTdry) - Vwtr * DENSwtr)
                     / DENSoil   
       12: Soil = Voil / PHIe

Only in rare cases will Soil + Swtr = 1.00 - the balance is Sgas, usually air that entered the core during transport and storage.
 

SAMPLE CORE ANALYSIS REPORT

02181815W4R

#27771

780118

 

Revised Analysis - Soil and Swtr from Original Analysis

S#

Top

Base

Len

Kmax

K90

Kvert

Poros

GrDen

BkDen

Soil

Swtr

Lithology

 

feet

feet

feet

mD

mD

mD

frac

Kg/m3

Kg/m3

frac

frac

 

1

3499.19

3500.17

0.98

370.0

316.0

264.0

0.255

2850

2378

0.129

0.448

SS VF

2

3500.17

3501.16

0.98

445.0

425.0

326.0

0.248

2680

2263

0.123

0.450

SS VF

3

3501.16

3502.17

1.02

764.0

751.0

231.0

0.248

2670

2256

0.111

0.520

SS VF

4

3502.17

3503.16

0.98

445.0

417.0

127.0

0.234

2670

2279

0.129

0.479

SS VF

5

3503.16

3503.88

0.72

479.0

411.0

84.0

0.241

2700

2290

0.110

0.504

SS VF PRY

6

3503.88

3504.57

0.69

860.0

790.0

172.0

0.242

2680

2273

0.118

0.466

SS VF

7

3504.57

3504.67

0.10

 

0.1

0.1

 

 

 

 

 

SHALE

8

3504.67

3505.26

0.59

 

0.1

0.1

 

 

 

0.151

0.398

RUBBLE

9

3505.26

3505.49

0.23

486.0

402.0

261.0

0.246

2670

2259

0.134

0.358

SS VF SH INC

10

3505.49

3505.98

0.49

355.0

326.0

8.3

0.207

2640

2301

0.143

0.268

SS VF SHBKS

11

3505.98

3506.96

0.98

376.0

192.0

32.2

0.240

2650

2254

0.131

0.471

SS VF

12

3506.96

3507.88

0.92

250.0

245.0

17.6

0.218

2640

2282

0.156

0.399

SS VF CARB INC

13

3507.88

3508.47

0.59

491.0

0.1

0.1

0.237

 

 

0.119

0.389

SS VF

14

3508.47

3508.87

0.39

304.0

0.1

0.1

0.219

 

 

0.136

0.422

SS VF CARB BK

15

3508.87

3509.88

1.02

309.0

288.0

127.0

0.230

2850

2425

0.132

0.440

SS VF

16

3509.88

3510.87

0.98

845.0

340.0

135.0

0.237

2660

2267

0.131

0.323

SS VF SH INC

17

3510.87

3511.88

1.02

298.0

287.0

75.3

0.218

2650

2290

0.146

0.422

SS VF SH INC

18

3511.88

3512.87

0.98

139.0

0.1

0.1

0.208

2650

2307

0.103

0.354

SS VF

19

3512.87

3513.79

0.92

139.0

0.1

0.1

0.174

 

 

0.073

0.418

SS VF

20

3513.79

3514.38

0.59

 

0.1

0.1

 

 

 

0.096

0.441

RUBBLE

21

3514.38

3515.07

0.69

65.1

0.1

0.1

0.257

 

 

0.119

0.387

SS VF

22

3515.07

3515.16

0.10

 

0.1

0.1

 

 

 

 

 

SHALE

23

3515.16

3516.18

1.02

1050.0

385.0

385.0

0.254

2670

2246

0.044

0.492

SS VF

24

3516.18

3516.77

0.59

385.0

471.0

471.0

0.220

2660

2295

0.042

0.501

SS VF

25

3516.77

3517.46

0.69

835.0

183.0

183.0

0.237

2670

2274

0.050

0.531

SS VF CARB INC

26

3517.46

3518.28

0.82

901.0

644.0

644.0

0.238

2650

2257

0.046

0.487

SS VF

27

3518.28

3519.07

0.79

438.0

103.0

103.0

0.240

2690

2284

0.079

0.494

SS VF CARB INC

28

3519.07

3519.99

0.92

1430.0

278.0

278.0

0.251

2660

2243

0.063

0.501

SS VF

29

3519.99

3520.58

0.59

 

0.1

0.1

 

 

 

0.052

0.563

RUBBLE

30

3520.58

3521.46

0.89

1050.0

951.0

951.0

0.258

2570

2165

0.055

0.516

SS VF

31

3521.46

3522.48

1.02

382.0

61.5

61.5

0.210

2690

2335

0.064

0.450

SS M P/SCARB INC

32

3522.48

3523.47

0.98

570.0

48.9

48.9

0.186

2680

2368

0.058

0.408

SS M P/SCARB INC

33

3523.47

3524.48

1.02

 

0.1

0.1

 

 

 

0.082

0.411

RUBBLE

34

3524.48

3525.47

0.98

3149.0

321.0

321.0

0.209

2590

2258

0.051

0.391

SS VF

35

3525.47

3526.48

1.02

 

0.1

0.1

 

 

 

0.073

0.360

RUBBLE

36

3526.48

3527.47

0.98

285.0

48.8

18.8

0.170

2690

2403

0.046

0.481

SS M P/S

37

3527.47

3528.16

0.69

193.0

0.1

0.1

0.169

2770

2471

0.042

0.548

SS M P/S CARB

38

3528.16

3528.88

0.72

 

0.1

0.1

 

 

 

0.066

0.462

RUBBLE

 

 

 

 

 

 

 

 

 

 

 

 

 

Arithmetic Averages

0.78

602.9

228.6

140.2

0.227

2679

2297

0.095

0.443

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Use the oil saturation (Soil) data in this core analysis example to find the oil - water contact.
 

Copyright © E. R. (Ross) Crain, P.Eng.  email
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